Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato}-κ3 N,N′,O 1;κ2 N,O 1-zinc(II) dihydrate
نویسندگان
چکیده
In the title mononuclear Zn(II) complex, [Zn(C(13)H(19)N(2)O(2))(2)]·2H(2)O, the Zn(II) atom is coordinated by two O atoms and three N atoms from two crystallographically different Schiff base ligands in a distorted trigonal-bipyramidal environment. One O and two N atoms constitute the base of the pyramid, and one O and one N atoms occupy the apical positions. Inter-molecular O-H⋯O and O-H⋯N hydrogen bonds between the lattice water mol-ecules and N/O atoms of the Schiff base ligands stabilize the conformation, whereas inter-molecular O-H⋯O hydrogen bonds between the two lattice water mol-ecules lead to a chain structure in [001].
منابع مشابه
Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato-κ3 N,N′,O 1}nickel(II)
The centrosymmetric title complex, [Ni(C(13)H(19)N(2)O(2))(2)], is a mononuclear nickel(II) complex. The Ni(II) atom is coordinated by four N atoms and two O atoms of two deprotonated Schiff base ligands, forming a slightly distorted octa-hedral coordination configuration, in which the tertiary N atoms occupy the axial positions.
متن کاملBis[μ-4-(dimethylamino)benzoato]-κ3 O,O′:O;κ3 O:O,O′-bis{aqua[4-(dimethylamino)benzoato-κ2 O,O′](nicotinamide-κN 1)cadmium(II)}
In the centrosymmetric dimeric Cd(II) title compound, [Cd(2)(C(9)H(10)NO(2))(4)(C(6)H(6)N(2)O)(2)(H(2)O)(2)], each seven-coordin-ated Cd(II) atom is chelated by the carboxyl-ate groups of the two 4-(dimethyl-amino)-benzoate (DMAB) anions; the two monomeric units are bridged through the two O atoms of the two carboxyl groups. In the crystal structure, inter-molecular O-H⋯O, N-H⋯O and C-H⋯O hydro...
متن کاملBis(μ-cyclohexane-1,3-dicarboxylato)-κ3 O 1:O 4,O 4′;κ3 O 1,O 1′:O 4-bis[aqua(1,10-phenanthroline-κ2 N,N′)zinc(II)]
The cyclo-hexane-1,3-dicarboxyl-ate dianion in the dinuclear centrosymmetric title compound, [Zn(2)(C(8)H(10)O(4))(2)(C(12)H(8)N(2))(2)(H(2)O)(2)], has a chair conformation with both carboxyl-ate groups in equatorial positions. One carboxyl-ate group chelates a Zn(II) atom, whereas the other binds through one O atom only to confer a six-coordinate status to the N-heterocycle-chelated water-coor...
متن کاملBis{2-[3-(dimethylamino)propyliminomethyl]-4,6-dihydroselenophenolato}zinc(II)
In the title complex, [Zn(C(12)H(17)N(2)OSe(2))(2)], the Zn(II) ion is six-coordinated by two N,N',O-tridentate Schiff base ligands, resulting in a slightly distorted trans-ZnO(2)N(4) octa-hedral coordination for the metal ion.
متن کاملBis(acetato-κ2 O,O′)(2,2′:6′,2′′-terpyridine-κ3 N,N′,N′′)manganese(II) dihydrate
The Mn(II) ion in the title compound, [Mn(CH(3)CO(2))(2)(C(15)H(11)N(3))]·2H(2)O, is seven-coordinated in a considerably distorted penta-gonal-bipyramidal geometry by three N atoms of the tridentate 2,2':6',2''-terpyridine ligand and four O atoms from two acetate anions which chelate the Mn atom via two O atoms. The lateral pyridine rings are slightly inclined to the central pyridine ring, maki...
متن کامل